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INORGANIC REACTION MECHANISMS AN INTRODUCTION【2025|PDF下载-Epub版本|mobi电子书|kindle百度云盘下载】
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- JOHN O. EDWARDS 著
- 出版社: INC.
- ISBN:
- 出版时间:1964
- 标注页数:190页
- 文件大小:44MB
- 文件页数:203页
- 主题词:
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图书目录
Chapter 1 INTRODUCTION1
1-1 The Subject of this Book1
1-2 Stoichiometry2
1-3 Equilibria3
1-4 Reaction Rate5
1-5 Transition-State Theory8
1-6 Order and Reaction Mechanism10
1-7 Symbols11
Chapter 2 BINDING STRENGTH AND REACTION RATES:ACIDS,BASES,AND SOLVENTS14
2-1 Bronsted Theory14
2-2 Specific-Acid Catalysis15
2-3 General-Acid Catalysis17
2-4 Bronsted Equation18
2-5 Statistical Corrections20
2-6 Lewis Theory22
2-7 Other Definitions24
2-8 General Influence of Solvents25
2-9 Physical Properties of Solvents26
2-10 Chemical Nature of Solvents28
Chapter 3 BINDING STRENGTH AND REACTION RATES:LINEAR FREE-ENERGY RELA-TIONS31
3-1 Linear Free-Energy Relations32
3-2 Assumptions36
3-3 Mathematical Form37
3-4 Examples of LFER37
3-5 Problems with LFER40
3-6 Intermediates45
3-7 Kinetic Isotope Effects46
Chapter 4 NUCLEOPHILIC DISPLACEMENTS51
4-1 Types of Mechanism51
4-2 Rate Scales53
4-3 Rate Factors54
4-4 Orders of Nucleophilic Character57
4-5 Displacements on Phosphorus59
4-6 Displacements in Planar Complexes63
4-7 Discussion68
Chapter 5 NONRADICAL MECHANISMS FOR PEROXIDE REACTIONS73
5-1 Nucleophilic Displacements73
5-2 Peroxyanions as Nucleophiles81
5-3 Peroxyanions as Leaving Groups82
5-4 Peroxide Decomposition84
5-5 Hypohalite Reactions88
Chapter 6 REPLACEMENTS IN OCTAHEDRAL COMPLEXES90
6-1 Labile and Inert Complexes90
6-2 Crystal-Field Stabilization92
6-3 General Aspects95
6-4 Dissociation vs.Displacement100
6-5 Base Hydrolysis103
6-6 Chromium(Ⅲ)Compounds107
6-7 Complexes of Divalent Cations112
Chapter 7 ELECTRON-TRANSFER REACTIONS OF COMPLEXES115
7-1 Electron-Transfer Theory115
7-2 Outer-Sphere Exchange Reactions118
7-3 Bridge Mechanism120
7-4 Iron(Ⅱ)—Iron(Ⅲ)Exchange125
7-5 Two-Electron Transfers127
7-6 Noncomplementary Reactions128
7-7 Replacement through Redox Mechanism132
Chapter 8 REACTIONS OF OXYANIONS137
8-1 Factors Affecting Rates137
8-2 Oxygen Exchange142
8-3 Exchange between Phosphate and Water145
8-4 Induced Reactions146
8-5 Chromate-Arsenite Reaction149
8-6 Urea-Formation Reaction151
Chapter 9 FREE RADICAL REACTIONS154
9-1 Steady-State Approximation155
9-2 Decomposition of Persulfate155
9-3 Dinitrogen Pentoxide Decomposition158
9-4 Chain Reactions160
9-5 Hydrogen-Bromine Reaction163
9-6 Other Hydrogen-Halogen Reactions166
9-7 Persulfate-Peroxide Reaction170
Chapter 10 SOME UNSOLVED PROBLEMS174
10-1 General Problems174
10-2 Constituents of a Rate Law175
10-3 Trace-Metal Catalysis176
10-4 Problems in Phosphorus Displacements177
10-5 Replacements in Coordination Compounds180
10-6 Nitrosation Reactions181
10-7 Some Reactions to Study183
Index185
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